4 - 6 weeks if its a change of ownership (sometimes it will come thru quicker)
4 working days if the vehicle is registered to you and you order a duplicate over the phone paying £19 for the privilidge.
Use this link to see what date the last V5 was issued for your car:
www.dvla.gov.uk/vehiclelicence
(select vehicle enquiry)
If all else fails ring them on: 0870 2400010 to chase it up