You can only re mortgage your first property if you can show that you can afford the repayments.
If the lender knows you are buying to let, you pay a slightly higher interest rate.
The advantage of re mortgaging is you could buy the second one for cash at auction and get a good deal, or buy one in need of repair, where a mortgage wouldn't normally be given.
The lender will take account of the future rental income when deciding how much to lend.
There's probably some good info on here:
http://www.moneysavingexpert.com/mortgages
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