Originally Posted by Chipperx2
oilman, Am I right in saying that because the difference between the high and low grades in 5-30W (ie. 30-5 = 25) the molecules are less likely to be oxidised(or breakdown) than oils with say a 10-60W rating?
It's to do with stability.
The viscosity gap between 5w-30 = 25
The viscosity gap between 10w-60 = 50
The smaller the gap the more stable the oil as less VI Improvers are required.
Viscosity Index Improvers.
An oils viscosity will decrease as the engine temperature rises. Viscosity Index Improvers are added to reduce this thinning. They are a key addative in the production of multigrade oils.
VI Improvers are heat sensitive long chain, high molecular weight polymers that increase the relative viscosity of the oil at high temperatures. They work like springs, coiled at low temperatures and uncoiling at high temperatures. This makes the molecules larger (at high temps) which increases internal resistance within the thinning oil. They in effect "fight back" against the viscosity loss in the oil.
"Shearing"
The long chain molecules in VI Improvers are prone to "shearing" with use which reduces their ability to prevent the oil from losing viscosity. This "shearing" occurs when shear stress ruptures the long chain molecules and converts them to shorter, lower weight molecules. The shorter, lower weight molecules offer less resistance to flow and their ability to maintain viscosity is reduced.
This shearing not only reduces the viscosity of the oil but can cause piston ring sticking (due to deposits), increased oil consumption and increased engine wear.
Like basestock quality, VI Improvers also vary in quality. The best quality ones are normally found in synthetic oils (Group IV - PAO / Group V - Esters) and it is important to understand that the less of these in the oil the better the oil will stay in grade.
Which oils require more VI Improvers?
There are two scenarios where large amounts of these polymers are required as a rule.
Firstly in "wide viscosity" multigrades. By this I mean that the difference between the lower "W" number and the higher number is large for example 5w-50 (diff 45) and 10w-60 (diff 50) are what is termed as "wide viscosity" oils.
Narrow viscosity oils like 0w-30 (diff 30) or 5w-40 (diff 35) require far less VI Improvers and therefore are less prone to "shearing".
Secondly, mineral and hydrocracked (petroleum synthetic oils) require more VI Improvers than proper PAO/Ester (Group IV or V) synthetic oils as they are less thermally stable to begin with and this is due to the non-uniform molecules in petroleum oils as opposed to the uniformity of synthetics built in laboratories by chemists.
It is a fact that some synthetics require little or no VI Improvers to work as a multigrade due to their superior thermal stability.
Cheers
Simon